个人简历

刘兆洪，副教授，硕士生导师 研究方向：围绕过渡金属催化卡宾转移反应开展有机合成方法学研究 学习及工作经历： 2002.09 - 2006.06：四川大学华西药学院，理学学士 2006.07 - 2011.06：凯莱英医药集团,助理研究员，研发组长 2012.09 - 2018.06：东北师范大学化学学院,有机化学博士，指导老师：毕锡和教授 2019.03 - 东北师范大学化学学院 论文发表情况： 26. Zhaohong Liu, Paramasivam Sivaguru, Giuseppe Zanoni, Xihe Bi.* N-Triftosylhydrazones: A New Chapter for Diazo-Based Carbene Chemistry. Acc. Chem. Res. 2022, 55, 1763−1781. 25. Zhaohong Liu,# Hongwei Wang,# Giuseppe Zanoni, Paramasivam Sivaguru, Steven P. Nolan, Qingmin Song, Weijie Yu, Xinyu Jiang, Edward A. Anderson, Xihe Bi.* Silver-Catalyzed Site-Selective C(sp3)-H Benzylation of Ethers with N-triftosylhydrazones. Nat. Commun. 2022, 13, 1674. (# Contributed equally to this work). 24. Zhaohong Liu,# Yong Yang,# Xinyu Jiang,# Qingmin Song, Giuseppe Zanoni, Shaopeng Liu, Xihe Bi.* Dearomative [4 + 3] Cycloaddition of Furans with Vinyl-N-triftosylhydrazones by Silver Catalysis: Stereoselective Access to oxa-Bridged Seven-membered Bicycles. Org. Chem. Front. 2022, 9, 2444–2452. (# Contributed equally to this work). 23. Zhongxue Fang, Yiming Ma, Shaopeng Liu, Huricha Bai, Shuang Li, Yongquan Ning,* Giuseppe Zanoni, and Zhaohong Liu.* Silver-Catalyzed [4+3] Cycloaddition of 1,3-dienes with vinyl-N-triftosylhydrazones: A practical approach to 1,4-cycloheptadienes. Org. Chem. Front. 2022, 9, 4426–4434. 22. Xiaolong Zhang,# Yongquan Ning,# Zhaohong Liu,# Shuang Li, Giuseppe Zanoni, and Xihe Bi.* Defluorinative Carboimination of Trifluoromethyl Ketones. ACS Catal. 2022, 12, 8802−8810. (# Contributed equally to this work). 21. Yong Yang,# Zhaohong Liu,# Paramasivam Sivaguru, Xihe Bi.* The Merger of Vinyl-N-Triftosylhydrazones and Silver Catalysis to Enable Stereoselective Vinylcyclopropanation of Alkenes. Chem Catal. 2022, 2, 563–577. (# Contributed equally to this work). 20. Long Zheng, Zhanjing Wang, Chen Li, Yong Wu,* Zhaohong Liu,* Yongquan Ning.* The azidosulfonylation of terminal alkynes leading to β-azidovinyl sulfones. Chem. Commun. 2021, 57, 9874–9877. 19. Xinyu Zhang, Qi Zhang, Linxuan Li, Shanshan Cao, Zhaohong Liu,* Giuseppe Zanoni, Yongquan Ning, and Yong Wu.* Fluorocyclization of Allyl Alcohols and Amines to Access 3‑Functionalized Oxetanes and Azetidines. Org. Lett. 2021, 23, 3674−3679. 18. Binbin Liu, Qingmin Song, Zhaohong Liu,* Zikun Wang.* Silver-Catalyzed Oxyphosphorylation of Unactivated Alkynes. Adv. Synth. Catal. 2021, 363, 3214– 3219. 17. Xiaolong Zhang,# Zhaohong Liu,# Xihe Bi.* Silver Carbenoids Derived from Diazo compounds: A Historical Perspective on Challenges and Opportunities. Chem Catal. 2021, 1, 599–630. (# Contributed equally to this work). 16. Yeming Wang,* Hongwei Wang, Zhaohong Liu.* Research Progress on EWG-Substituted N-Arylsulfonylhydrazones as the Diazo Compound Precursor. Acta Chim. Sinica 2021, 79, 1085–1096. 15. Zhaohong Liu, # Shanshan Cao,# Weijie Yu, Jiayi Wu, Fanhua Yi, Edward A. Anderson, Xihe Bi.* Site-Selective C–H Benzylation of Alkanes with N-Triftosylhydrazones Leading to Alkyl Aromatics. Chem 2020, 6, 2110–2124. (# Contributed equally to this work). 14. Zhaohong Liu,# Shanshan Cao,# Jiayi Wu, Giuseppe Zanoni, Paramasivam Sivaguru, Xihe Bi.* Palladium(II)-Catalyzed Cross-Coupling of Diazo Compounds and Isocyanides to Access Ketenimines. ACS Catal. 2020, 10, 12881−12887. (# Contributed equally to this work). 13. Yu Wang, Kongshuang Tang, Zhaohong Liu,* Yongquan Ning.* Disulfonation of terminal alkynes for 1,2-bisulfonylethenes. Chem. Commun. 2020, 56, 13141–13144. 12. Yue, Sun, Rui Guan, Zhaohong Liu,* Yeming Wang.* Recent Advances in Hydroboration of Alkenes Catalyzed by Fe, Co and Ni. Chin. J. Org. Chem. 2020, 40, 899–912. 11. Shanshan Cao, Zhaohong Liu,* Haiyan Yuan, Jingping Zhang,* Xihe Bi.* Computational Studies on Reaction Mechanism of the Catalyst-Controlled Selective Insertion of Metal Carbenoids into C–C and C–H Bonds of 1,3-Dicarbonyl Compounds. Chin. J. Org. Chem. 2020, 40, 2468–2475. 10. Xinyu Zhang,# Zhaohong Liu,# Xiangyu Yang, Yuanqing Dong, Matteo Virelli, Giuseppe Zanoni, Edward A. Anderson, Xihe Bi.* Use of Trifluoroacetaldehyde N-Tfsylhydrazone as a Trifluorodiazoethane Surrogate and Its Synthetic Applications. Nat. Commun. 2019, 10, 284. (# Contributed equally to this work). 9. Zhaohong Liu, Kaki Raveendra Babu, Feng Wang, Yang Yang, Xihe Bi.* Influence of Sulfonyl Substituents on the Decomposition of N-sulfonylhydrazones at Room Temperature, Org. Chem. Front. 2019, 6, 121–124. 8. Zhaohong Liu, Paramasivam Sivaguru, Giuseppe Zanoni, Edward A. Anderson, Xihe Bi.* Catalyst-Dependent Chemoselective Formal Insertion of Diazo Compounds into C-C or C-H Bonds of 1,3-Dicarbonyl Compounds. Angew. Chem. Int. Ed. 2018, 57, 8927–8931. 7. Zhaohong Liu, Xinyu Zhang, Matteo Virelli, Giuseppe Zanoni, Edward A. Anderson, Xihe Bi.* Silver-Catalyzed Regio- and Stereoselective Formal Carbene Insertion into Unstrained C-C σ-Bonds of 1,3-Dicarbonyls. iScience 2018, 8, 54–60. 6. Zhaohong Liu, Xinyu Zhang, Giuseppe Zanoni, Xihe Bi.* Silver-Catalyzed Cyclopropanation of Alkenes Using N‑Nosylhydrazones as Diazo Surrogates. Org. Lett. 2017, 19, 6646−6649. 5. Zhaohong Liu, # Qiangqiang Li, # Yang Yang, Xihe Bi.* Silver(I)-Promoted Insertion into X–H (X = Si, Sn, and Ge) Bonds with N-Nosylhydrazones. Chem. Commun. 2017, 53, 2503–2506. (# Contributed equally to this work). 4. Zhaohong Liu, Qiangqiang Li, Peiqiu Liao, Xihe Bi.* Silver-Catalyzed [2+1] Cyclopropenation of Alkynes with Unstable Diazoalkanes: N-Nosylhydrazones as Room-Temperature Decomposable Diazo Surrogates, Chem. Eur. J. 2017, 23, 4756 – 4760. 3. Yang Yang,# Zhaohong Liu,# Alessio Porta, Giuseppe Zanoni, Xihe Bi.* Alkynyl N-Nosylhydrazones: Easy Decomposition to Alknynl Diazomethanes and Application in Allene Synthesis. Chem. Eur. J. 2017, 23, 9009–9013. (# Contributed equally to this work). 2. Zhaohong Liu, Binbin Liu, Xue-Feng Zhao, Yan-Bo Wu,* Xihe Bi,* et al. Silver-Catalyzed Cross-Olefination of Donor and Acceptor Diazo Compounds: Use of N-Nosylhydrazones as Diazo Surrogate, Eur. J. Org. Chem. 2017, 928–932. 1. Zhaohong Liu, Peiqiu Liao, Xihe Bi.* Lewis and Brønsted Acid Cocatalyzed Reductive Deoxyallenylation of Propargylic Alcohols with 2-Nitrobenzenesulfonylhydrazide. Chem. Eur. J. 2014, 20, 17277 – 17281.