职  称:教授
研究方向:金属有机化学
办公电话:85099551
办公地点:化学楼233

个人简历

教授、博导 教育部“长江学者奖励计划”青年学者(2016) 国家自然科学基金委“优青”(2015) 教育部新世纪优秀人才(2013) 德国洪堡学者(2006) 1996年09月- 2000年07月 东北师范大学 化学 学士 2000年09月- 2006年07月 东北师范大学 有机化学 博士 2006年08月- 2006年09月 歌德学院(德国 波恩) 德语学习 2006年10月- 2008年12月 德国波恩大学凯库勒研究所 洪堡学者 2005年07月- 现今 东北师范大学 化学学院 讲师、副教授、教授 毕锡和于2008年回国开展独立的研究工作,研究领域为有机合成化学,聚焦银催化有机化学反应研究,取得了系列原创性成果,在过去五年发表通讯作者论文五十余篇。研究成果被选为封面文章、VIP论文、Hot Paper,或被SYNFORM,Synfacts,ChemViews Magazine,Chin. JOC,Org. Chem. Highlights等评述或报道三十余次,得到了国内外同行的关注和认可。毕锡和相继于2016年入选教育部“长江学者奖励计划”青年学者、2015年获得国家自然科学基金委“优秀青年科学基金”、2013年入选教育部“新世纪优秀人才支持计划”,并获得Thieme Chemistry Journals Award(2014)、吉林省中青年科技创新领军人才、德国洪堡学者、“东师学者”青年学术骨干等荣誉和奖励。 这是一个年轻、和睦团结并富有朝气的研究团队,具备很好的研究基础,热忱欢迎有志投身于科学研究事业的青年朋友加入到这个团队中来,共同探索自然的奥秘。 更多信息请浏览"课题组"主页:http://www.bigroup.top 代表性论文: 1. Yongquan Ning, Qinghe Ji, Peiqiu Liao, Edward A. Anderson, and Xihe Bi* Silver-Catalyzed Stereoselective Aminosulfonylation of Alkynes Angew. Chem. Int. Ed. 2017, 56, 13805–13808. * Highlighted by Chin. J. Org. Chem. 2. G.-C. Fang, X.-H. Bi* Silver-catalysed reactions of alkynes: recent advances Chem. Soc. Rev. 2015, 44, 8124–8173. 3. J.-Q. Liu, Z.-H. Liu, P.-Q. Liao, L. Zhang, T. Tu, X.-H. Bi* Silver-Catalyzed Cross-Coupling of Isocyanides and Active Methylene Compounds by a Radical Process Angew. Chem. Int. Ed. 2015, 54, 10618–10622. 4. Z.-H. Liu, J.-Q. Liu, L. Zhang, P.-Q. Liao, J.-N. Song and X.-H. Bi* Silver(I)-Catalyzed Hydroazidation of Ethynyl Carbinols: Synthesis of 2-Azidoallyl Alcohols Angew. Chem. Int. Ed. 2014, 53, 5305–5309. * Featured in Front Cover * Highlighted by Synform * Highlighted by Chin. J. Org. Chem. 5. Z.-X. Fang, J.-Q. Liu, Q. Liu and X.-H. Bi* [3+2] Cycloaddition of Propargylic Alcohols and α-Oxo Ketene Dithioacetals: A Strategy to Multifunctionalized Cyclopentadienes Angew. Chem. Int. Ed., 2014, 53, 7209–7213. * Featured in Inside Cover * Highlighted by Chin. J. Org. Chem. 6. J.-Q. Liu, Z.-X. Fang, Q. Zhang,* Q. Liu and X.-H. Bi* Silver-Catalyzed Isocyanide-Alkyne Cycloaddition: A General and Practical Method to Oligosubstituted Pyrroles Angew. Chem. Int. Ed. 2013, 52, 6953–6957. * VIP Paper * Highlighted by Synfacts (2013, 9, 942) * Highlighted by Chin. J. Org. Chem. 7. L. Zhang, X.-H. Bi*, X.-X. Guan, X.-Q. Li, Q. Liu*, B.-D. Barry, P.-Q. Liao Chemoselective Oxidative C(CO)−C(methyl) Cleavage of Methyl Ketones to Aldehydes Catalyzed by CuI with Molecular Oxygen Angew. Chem. Int. Ed. 2013, 52, 11303–11307. * Featured in Inside Cover * Highlighted by Synform * Highlighted by Chin. J. Org. Chem. * Highlighted by Org. Chem. Highlights.

社会兼职

获奖情况 (数据来源:科学技术处、社会科学处)

  • 2018-11-07 吉林省科学技术奖自然科学奖一等奖
  • 2015-10-20 吉林省自然科学学术成果奖二等奖

教学信息 (数据来源:教务处)

  • 有机化学(I)
  • 19有机
  • 20级有机
  • 21级有机化学学硕
  • 有机化学A-1
  • 有机化学
  • 有机化学(材料物理班)
  • 有机化学(材料物理)
  • 合成化学实验
  • 有机化学A-2
  • 有机化学(II)

科研信息 (数据来源:科学技术处、社会科学处)

  • 项目:
  • 1. 银/铜催化的新型卡宾转化研究,国家自然科学基金项目,2023年
  • 2. 银催化烷烃分子间 C(sp3)-H 键活化及反应,其他课题,2020年
  • 3. 烯基叠氮化学的探索与开发,国家自然科学基金项目,2019年
  • 4. 银活化端炔在DNA自旋标记技术中的应用,国际合作项目,2019年
  • 5. 基于现场生成亚胺自由基的官能团迁移反应研究,其他课题,2019年
  • 6. 银催化多组分条件产生亚胺自由基与反应研究,国家自然科学基金项目,2018年
  • 7. 基于磺酰腙低温分解的链酮增碳反应研究,省、市、自治区科技项目,2018年
  • 8. 银催化异氰[3+2]环加成反应研究,其他课题,2017年
  • 9. 光促C-H硝化反应研究,其他课题,2017年
  • 10. 有机合成反应研究,国家自然科学基金项目,2015年
  • 11. 含硫烯基联烯的新型串联反应研究,其他课题,2015年
  • 12. 银催化炔丙醇与异氰的新反应研究,其他课题,2015年
  • 13. 基于‘官能化炔’的新反应研究,省、市、自治区科技项目,2014年
  • 14. 新型串联成环反应研究,其他课题,2014年
  • 15. 教育部新世纪优秀人才支持计划NCET-13-0714,主管部门科技项目,2013年
  • 16. 炔丙醇与异氰的联烯化、烯化反应研究,国家自然科学基金项目,2013年
  • 17. 基于含硫烯基联烯的新型串联反应研究,企事业单位委托科技项目,2013年
  • 18. 生物友好的Huisgen反应催化剂的研究:基于氮杂环卡宾铜配合物以及氧化亚铜纳米粒子的探索,企事业单位委托科技项目,2011年
  • 19. 基于双烷硫基α-烯基联烯的成环反应研究,国家自然科学基金项目,2011年
  • 20. 基于铁催化的吡咯类化合物的合成方法研究(实验室开放课题),企事业单位委托科技项目,2011年
  • 21. 基于Cu(I)-NHC配合物的生物友好的端炔与叠氮化物Huisgen反应催化剂的研究(实验室开放课题),企事业单位委托科技项目,2010年
  • 22. 基于铁催化的吡咯类化合物的合成研究,省、市、自治区科技项目,2010年
  • 23. 基于Cu(1)-NHC配合物的生物友好的端炔与叠氮化物Huisgen反应催化剂的研究,主管部门科技项目,2010年
  • 24. 活体细胞标记技术研究,企事业单位委托科技项目,2010年
  • 25. 应用于活细胞标记的催化剂的研究,国务院其他部门,2009年
  • 26. 基于Cu(I)-NHC配合物的生物友好的端炔与叠氮化物Huisgen反应催化剂的研究,省、市、自治区科技项目,2009年
  • 27. 基于Cu(I)-NHC配合物的生物友好的端炔与叠氮化物Huisgen反应催化剂的研究(NSFC),国家自然科学基金项目,2009年
  • 专著:
  • 1. Silver Catalysis in Organic Synthesis,WILEY-VCH,21-1年
  • 2. 有机化学实验教程,清华大学出版社,01-2年
  • 论文:
  • 1. Rhodium-Catalyzed One-Carbon Ring Expansion of Aziridines with Vinyl-N-triftosylhydrazones for the Synthesis of 2-Vinyl Azetidines,ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2024年
  • 2. Silver-Catalyzed Dearomative Skeletal Editing of Indazoles by Donor Carbene Insertion,CHEMISTRY-A EUROPEAN JOURNAL,2024年
  • 3. Silver-catalyzed direct conversion of epoxides into cyclopropanes using N-triftosylhydrazones,NATURE COMMUNICATIONS,2024年
  • 4. Rh-catalyzed asymmetric cyclopropanation of benzofurans with trifluoromethyl N-triftosylhydrazones,J FLUORINE CHEM,2024年
  • 5. Defluorinative 1,3-Dienylation of Fluoroalkyl N-Triftosylhydrazones with Homoallenols,CHEMISTRY-A EUROPEAN JOURNAL,2023年
  • 6. Silver-catalyzed vinylcarbene insertion into Si-H bonds with vinyl N-triftosylhydrazones leading to allylsilanes,Organic Chemistry Frontiers,2023年
  • 7. Skeletal Editing of (Hetero)Arenes Using Carbenes,CHEMISTRY-A EUROPEAN JOURNAL,2023年
  • 8. Asymmetric [2+1] cycloaddition of difluoroalkyl-substituted carbenes with alkenes under rhodium catalysis: Synthesis of chiral difluoroalkyl-substituted cyclopropanes,iScience,2023年
  • 9. Ligand-enabled silver-catalyzed carbene insertion into the N-H bond of aliphatic and electron-rich aromatic amines,Organic Chemistry Frontiers,2023年
  • 10. Site-Selective C-H Allylation of Alkanes: Facile Access to Allylic Quaternary sp3-Carbon Centers,ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2023年
  • 11. Synthesis of Propargyl Boranes via Silver Catalyzed Insertion of Alkynyl Carbene into B-H Bond,CHEMCATCHEM,2023年
  • 12. Silver catalysis in organic synthesis: A computational view,ADV ORGANOMET CHEM,2023年
  • 13. Chemoselective carbene insertion into the N-H bonds of NH3·H2O,NATURE COMMUNICATIONS,2022年
  • 14. Highly electrophilic silver carbenes,CHEMICAL COMMUNICATIONS,2022年
  • 15. Silver-Catalyzed Vinylcarbene Insertion into C-C Bonds of 1,3-Diketones with Vinyl-N-triftosylhydrazones,ORGANIC LETTERS,2022年
  • 16. Carbodefluorination of fluoroalkyl ketones via a carbene-initiated rearrangement strategy,NATURE COMMUNICATIONS,2022年
  • 17. Defluorinative Carboimination of Trifluoromethyl Ketones,ACS CATALYSIS,2022年
  • 18. N-Triftosylhydrazones: A New Chapter for Diazo-Based Carbene Chemistry,ACCOUNTS CHEM RES,2022年
  • 19. Dearomative [4 + 3] cycloaddition of furans with vinyl-N-triftosylhydrazones by silver catalysis: stereoselective access to oxa-bridged seven-membered bicycles,Organic Chemistry Frontiers,2022年
  • 20. Direct gem-Difluoroalkenylation of X-H Bonds with Trifluoromethyl Ketone N-Triftosylhydrazones for Synthesis of Tetrasubstituted Heteroatomic gem-Difluoroalkenes,CHEMISTRY-A EUROPEAN JOURNAL,2022年
  • 21. Silver-catalyzed site-selective C(sp3)-H benzylation of ethers with N-triftosylhydrazones,NATURE COMMUNICATIONS,2022年
  • 22. [4 + 1] Annulation of in situ generated azoalkenes with amines: A powerful approach to access 1-substituted 1,2,3-triazoles,CHINESE CHEM LETT,2022年
  • 23. The merger of vinyl-N-triftosylhydrazones and silver catalysis to enable stereoselective vinylcyclopropanation of alkenes,Chem catalysis,2022年
  • 24. Silver-catalyzed cyclopropanation of alkenes with alkynyl N-nosylhydrazones leading to alkynyl cyclopropanes,CHEMICAL COMMUNICATIONS,2022年
  • 25. A Carbene Strategy for Progressive (Deutero)Hydrodefluorination of Fluoroalkyl Ketones,ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022年
  • 26. Ag-Catalyzed Insertion of Alkynyl Carbenes into C-C Bonds of β-Ketocarbonyls: A Formal C(sp2) Insertion,ORGANIC LETTERS,2022年
  • 27. Catalytic Asymmetric C(sp3)-H Carbene Insertion Approach to Access Enantioenriched 3-Fluoroalkyl 2,3-Dihydrobenzofurans,ACS CATALYSIS,2021年
  • 28. Defluorinative [4 + 1] annulation of perfluoroalkyl N-mesylhydrazones with primary amines provides 5-fluoroalkyl 1,2,3-triazoles,GREEN CHEMISTRY,2021年
  • 29. Fluoroalkyl N-sulfonyl hydrazones: An efficient reagent for the synthesis of fluoroalkylated compounds,SCIENCE CHINA-CHEMISTRY,2021年
  • 30. Synthetic exploration of sulfinyl radicals using sulfinyl sulfones,NATURE COMMUNICATIONS,2021年
  • 31. Silver carbenoids derived from diazo compounds: A historical perspective on challenges and opportunities,Chem catalysis,2021年
  • 32. Silver N-heterocyclic carbenes: emerging powerful catalysts,TRENDS IN CHEMISTRY,2021年
  • 33. Editorial: Special Collection of Silver Catalysis in Organic Synthesis,CHEMCATCHEM,2021年
  • 34. Fluoroalkyl N-Triftosylhydrazones as Easily Decomposable Diazo Surrogates for Asymmetric [2 + 1] Cycloaddition: Synthesis of Chiral Fluoroalkyl Cyclopropenes and Cyclopropanes,ACS CATALYSIS,2021年
  • 35. Silver-catalyzed unstrained C(CO)–alkyl bond scission via [3+2]/retro-[3+2] cycloaddition of ketones with N-isocyanoiminotriphenylphosphorane,SCIENCE CHINA-CHEMISTRY,2021年
  • 36. New Strategies for the Synthesis of Aliphatic Azides,CHEMICAL REVIEWS,2021年
  • 37. Computational Insights into Different Mechanisms for Ag-, Cu-, and Pd-Catalyzed Cyclopropanation of Alkenes and Sulfonyl Hydrazones,CHEMISTRY-A EUROPEAN JOURNAL,2021年
  • 38. Palladium(II)-Catalyzed Cross-Coupling of Diazo Compounds and Isocyanides to Access Ketenimines,ACS CATALYSIS,2020年
  • 39. Site-Selective C-H Benzylation of Alkanes with N-Triftosylhydrazones Leading to Alkyl Aromatics,CHEM,2020年
  • 40. 催化剂调控的金属卡宾与1,3-二羰基化合物选择性C—C键与C—H键插入反应机理的理论研究,CHINESE J ORG CHEM,2020年
  • 41. AgN3-Catalyzed Hydroazidation of Terminal Alkynes and Mechanistic Studies,J AM CHEM SOC,2020年
  • 42. Neighbouring carbonyl group-assisted sequential 1,2-azide and 1,4-oxygen migrations of vinyl azides leading to a-azido ketones,Science China Chemistry,2020年
  • 43. Silver-Catalyzed Activation of Terminal Alkynes for Synthesizing Nitrogen-Containing Molecules,ACCOUNTS CHEM RES,2020年
  • 44. Cycloaddition of Trifluoroacetaldehyde N-Triftosylhydrazone (TFHZ-Tfs) with Alkynes for Synthesizing 3-Trifluoromethylpyrazoles,ORG LETT,2020年
  • 45. Synthesis of b-Difluoroalkyl Azides via Elusive 1,2-Azide Migration,CHEM,2020年
  • 46. Difluoroacetaldehyde N-Triftosylhydrazone (DFHZ-Tfs) as a Bench-Stable Crystalline Diazo Surrogate for Diazoacetaldehyde and Difluorodiazoethane,ANGEW CHEM INT EDIT,2020年
  • 47. Coupling of Trifluoroacetaldehyde N-Triftosylhydrazone with Organoboronic Acids for the Synthesis of gem-Difluoroalkenes,ORG LETT,2019年
  • 48. Transformation of Alkynes into a- or b-Difluorinated Alkyl Azides by an Efficient One-Pot Two-Step Procedure,ORG LETT,2019年
  • 49. Directed Copper-Catalyzed Intermolecular Aminative Difunctionalization of Unactivated Alkenes,J AM CHEM SOC,2019年
  • 50. Silver-Catalyzed anti-Markovnikov Hydroboration of C-C Multiple Bonds,ORG LETT,2019年
  • 51. Silver-Catalyzed Reduction of Quinolines in Water,ORG LETT,2019年
  • 52. Silver-Mediated [3+2] Cycloaddition of Alkynes and N-Isocyanoiminotriphenylphosphorane: Access to Monosubstituted Pyrazoles,ORG LETT,2019年
  • 53. Silver-Catalyzed C- to N-Center Remote Arene Migration,ACS CATALYSIS,2019年
  • 54. Cleavage of carbon-carbon bonds by radical reactions,CHEM SOC REV,2019年
  • 55. Direct Transformation of Terminal Alkynes into Amidines by a Silver-Catalyzed Four-Component Reaction,J AM CHEM SOC,2019年
  • 56. Use of trifluoroacetaldehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications,Nature Communications,2019年
  • 57. Influence of sulfonyl substituents on the decomposition of N-sulfonylhydrazones at room temperature,Organic Chemistry Frontiers,2019年
  • 58. Directed Copper-Catalyzed Intermolecular Heck-Type Reaction of Unactivated Olefins and Alkyl Halides,J AM CHEM SOC,2018年
  • 59. Silver-Catalyzed Regio- and Stereoselective Formal Carbene Insertion into Unstrained C-C a-Bonds of 1,3-Dicarbonyls,iScience,2018年
  • 60. Visible-Light-Induced Radical Polynitration of Arylboronic Acids: Synthesis of Polynitrophenols,SYNTHESIS-STUTTGART,2018年
  • 61. Catalyst-Dependent Chemoselective Formal Insertion of Diazo Compounds into C-C or C-H Bonds of 1,3-Dicarbonyl Compounds,ANGEW CHEM INT EDIT,2018年
  • 62. Silver-Promoted [3+1+1] Annulation of Isocyanoacetates with Nitrosoarenes,ASIAN JOURNAL OF ORGANIC CHEMISTRY,2018年
  • 63. Multifunctionalization of Unactivated Cyclic Ketones via Synergistic Catalysis of Copper and Diarylamine:: Access to Cyclic a-Enaminone,ORG LETT,2018年
  • 64. a-Substituted vinyl azides: an emerging functionalized alkene,CHEM SOC REV,2017年
  • 65. Silver-Catalyzed Cyclopropanation of Alkenes Using N-Nosylhydrazones as Diazo Surrogates,ORG LETT,2017年
  • 66. Rh(II)-Catalyzed Tandem Cyclization of Aliphatic N-Sulfonyl-1,2,3-triazoles and Alcohols for the Synthesis of 6-Alkoxy Piperidin-3-ones,ADV SYNTH CATAL,2017年
  • 67. Radical Enamination of Vinyl Azides: Direct Synthesis of N-Unprotected Enamines,ORG LETT,2017年
  • 68. Silver-Catalyzed Stereoselective Aminosulfonylation of Alkynes,ANGEW CHEM INT EDIT,2017年
  • 69. Silver-Mediated Direct C-H Cyanation of Terminal Alkynes with N-Isocyanoiminotriphenylphosphorane,ORG LETT,2017年
  • 70. Silver-Catalyzed Tandem C≡C Bond Hydroazidation/Radical Addition/Cyclization of Biphenyl Acetylene: One-Pot Synthesis of 6-Methyl Sulfonylated Phenanthridines,ORG LETT,2017年
  • 71. Alkynyl N-Nosylhydrazones: Easy Decomposition to Alknynl Diazomethanes and Application in Allene Synthesis,CHEM-EUR J,2017年
  • 72. Synthesis of 6-Substituted Piperidin-3-ones via Rh(II)-Catalyzed Transannulation of N-Sulfonyl-1,2,3-triazoles with Electron-Rich Aromatic Nucleophiles,ORG LETT,2017年
  • 73. Silver-Based Radical Reactions: Development and Insights,ADV SYNTH CATAL,2017年
  • 74. Silver-Catalyzed [2+1] Cyclopropenation of Alkynes with Unstable Diazoalkanes: N-Nosylhydrazones as Room-Temperature Decomposable Diazo Surrogates,CHEM-EUR J,2017年
  • 75. Azomethine-isocyanide [3+2] cycloaddition to imidazoles promoted by silver and DBU,CHEM COMMUN,2017年
  • 76. Highly efficient synthesis of N-sulfonylamidines via silver-catalyzed or metal-free thermally promoted denitrogenative amination of N-sulfonyl-1,2,3-triazoles,SYNTHESIS-STUTTGART,2017年
  • 77. Divergent Reactions between a-Imino Rhodium Carbenoids and 1,3-Diketones: Substrate-Controlled O-H versus C-H Insertion,EUR J ORG CHEM,2017年
  • 78. Silver-Catalyzed Cascade Reaction of b-Enaminones and Isocyanoacetates To Construct Functionalized Pyrroles,ORG LETT,2017年
  • 79. Silver(I)-promoted insertion into X-H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones,CHEM COMMUN,2017年
  • 80. Silver-mediated radical coupling reaction of isocyanides and alcohols/phenols in the presence of water: unprecedented hydration and radical coupling reaction sequence,ORG BIOMOL CHEM,2017年
  • 81. Silver-Catalyzed Cross-Olefination of Donor and Acceptor Diazo Compounds: Use of N-Nosylhydrazones as Diazo Surrogate,EUR J ORG CHEM,2017年
  • 82. Silver(I)-Promoted Radical Sulfonylation of Allyl/Propargyl Alcohols: Efficient Synthesis of r-Keto Sulfones,CHEMISTRY-AN ASIAN JOURNAL,2016年
  • 83. Silver-catalyzed organic reactions of isocyanides,TETRAHEDRON LETT,2016年
  • 84. Tandem O-H Insertion/[1,3]-Alkyl Shift of Rhodium Azavinyl Carbenoids with Benzylic Alcohols: A Route To Convert C-OH Bonds into C-C Bonds,ORG LETT,2016年
  • 85. Chemo- and regioselective reductive deoxygenation of 1-en-4-yn-ols into 1,4-enynes through FeF3 and TfOH co-catalysis,CHEM COMMUN,2016年
  • 86. Catalytic a-activation of carbon-carbon triple bonds: reactions of propargylic alcohols and alkynes,CHEM COMMUN,2016年
  • 87. Silver-catalysed reactions of alkynes: recent advances,CHEM SOC REV,2015年
  • 88. Radical Mechanism of Isocyanide-Alkyne Cycloaddition by Multicatalysis of Ag2CO3, Solvent, and Substrate,ACS CATALYSIS,2015年
  • 89. Silver-Catalyzed Cross-Coupling of Isocyanides and Active Methylene Compounds by a Radical Process,ANGEW CHEM INT EDIT,2015年
  • 90. Coinage-Metal-Catalyzed Reactions of Propargylic Alcohols,SYNTHESIS-STUTTGART,2015年
  • 91. Synthesis of 1,3,4-Trisubstituted Pyrazoles from a-(1,3-Dithian-2-yl) Enamine Ketones via [4+1] Cyclization,SYNLETT,2015年
  • 92. Silver-catalyzed cascade reaction of tosylmethyl isocyanide (TosMIC) with propargylic alcohols to (E)-vinyl sulfones: dual roles of TosMIC,ORG BIOMOL CHEM,2015年
  • 93. 银催化炔丙醇与芳基异腈交叉偶联反应:原子经济性合成N-芳基-2,3-联烯酰胺,CHINESE J ORG CHEM,2015年
  • 94. Silver-Catalyzed Tandem Hydroazidation/Alkyne-Azide Cycloaddition of Diynes with TMS-N3: An Easy Access to 1,5-Fused 1,2,3-Triazole Frameworks,ORG LETT,2015年
  • 95. Decarbonylative C-C Bond-Forming Reactions of Saccharins by Nickel Catalysis: Homocoupling and Cycloaddition,CHEM-EUR J,2015年
  • 96. Formation of Benzo[f]-1-indanone Frameworks by Regulable Intramolecular Annulations of gem-Dialkylthio Trienynes,ORG LETT,2015年
  • 97. 铜催化炔基溴与丙炔醇的偶联-异构化反应合成戊炔烯酮,CHINESE J ORG CHEM,2015年
  • 98. Iron-Catalyzed [4C+1N] Cyclization of 4-Acetylenic Ketones with Primary Amines: Synthesis of 5-(Aryl)alkylidene-4,5-dihydropyrroles,EUR J ORG CHEM,2014年
  • 99. Modular Synthesis of Sulfonyl Benzoheteroles by Silver-Catalyzed Heteroaromatization of Propargylic Alcohols with p-Toluenesulfonylmethyl Isocyanide (TosMIC): Dual Roles of TosMIC,ORG LETT,2014年
  • 100. Lewis and Bronsted Acid Cocatalyzed Reductive Deoxyallenylation of Propargylic Alcohols with 2-Nitrobenzenesulfonylhydrazide,CHEM-EUR J,2014年
  • 101. Silver-catalyzed cyclization of 2-pyridyl alkynyl carbinols with isocyanides: divergent synthesis of indolizines and pyrroles,CHEM COMMUN,2014年
  • 102. Base-Catalyzed Intramolecular 5-exo-dig Cyclization of 2-Propynyl-1,3-dicarbonyl Compounds: An Atom-Economic Route to Stereodefined 2-Methylene-2,3-dihydrofurans,EUR J ORG CHEM,2014年
  • 103. [3+2] Cycloaddition of Propargylic Alcohols and α-Oxo Ketene Dithioacetals: Synthesis of Functionalized Cyclopentadienes and Further Application in a Diels–Alder Reaction,ANGEW CHEM INT EDIT,2014年
  • 104. General Silver-Catalyzed Hydroazidation of Terminal Alkynes by Combining TMS-N3 and H2O: Synthesis of Vinyl Azides,ORG LETT,2014年
  • 105. Mechanistic understanding of domino cyclization between gem-dialkylthio vinylallenes and benzylamine towards economic synthesis: a computational study,GREEN CHEM,2014年
  • 106. Silver(I)-Catalyzed Hydroazidation of Ethynyl Carbinols: Synthesis of 2-Azidoallyl Alcohols,ANGEW CHEM INT EDIT,2014年
  • 107. Catalytic C − H a - Trifluoromethylation of a ,b-Unsaturated Carbonyl Compounds,ORG LETT,2014年
  • 108. Silver-Catalyzed Cross-Coupling of Propargylic Alcohols with Isocyanides: An Atom-Economical Synthesis of 2,3-Allenamides,CHEM-EUR J,2014年
  • 109. Synthesis of Dihydrothiophenes and Thiophenes by the Strategic Use of 2-Vinylidene-1,3- dithiolane as a Masked Thiolate Anion,EUR J ORG CHEM,2014年
  • 110. Chemoselective Oxidative C(CO)-C(methyl) Bond Cleavage of Methyl Ketones to Aldehydes Catalyzed by CuI with Molecular Oxygen,ANGEW CHEM INT EDIT,2013年
  • 111. An Atom-Economic Route to Thiophenes and 2,2’-Bithiophenes by Intramolecular Transannulation of gem-Dialkylthio Enynes,ORG LETT,2013年
  • 112. Cu(II)-catalyzed cyclization of a-diazo-b-oxoamides with amines leading to pyrrol-3(2H)-ones,CHEM COMMUN,2013年
  • 113. Iron(III)-catalyzed dehydration C(sp2)-C(sp2) coupling of tertiary propargyl alcohols and α-oxo ketene dithioacetals: A new route to gem-bis(alkylthio)-substituted vinylallenes,SYNTHESIS-STUTTGART,2013年
  • 114. Silver-Catalyzed Isocyanide-Alkyne Cycloaddition: A General and Practical Method to Oligosubstituted Pyrroles,ANGEW CHEM INT EDIT,2013年
  • 115. Regiospecific 6-Endo-Annulation of in situ Generated 3,4-Dienamides/Acids: Synthesis of δ-Lactams and δ-Lactones,ORG LETT,2013年
  • 116. Solvent-controlled, regio-switchable formation of 3-/5-arylaminopyrazole isomer in cyclocondensation of β-aminoenones with hydrazides: intermolecular hydrogen bonding plays a role,RSC ADVANCES,2013年
  • 117. Recent developments of ketene dithioacetal chemistry,CHEM SOC REV,2013年
  • 118. Cu(II)-catalyzed cyclization of α-diazo-β-oxoamides with amines leading to pyrrol-3(2H)-ones,CHEM COMMUN,2013年
  • 119. Direct C(sp2)–H chlorination of ketene dithioacetals using FeCl3 as the chloride source and PhI(OAc)2 as an oxidant,CHINESE SCI BULL,2012年
  • 120. gem-Dialkylthio vinylallenes: alkylthio-regulated reactivity and application in the divergent synthesis of pyrroles and thiophenes,CHEM COMMUN,2012年
  • 121. Intramolecular hydrogen bonding-assisted cyclocondensation of α-diazoketones with various amines: a strategy for highly efficient Wolff 1,2,3-triazole synthesis,CHEM COMMUN,2012年
  • 122. Synthesis of N-sulfonylazetidin-2-imines via the Copper(I) Oxide Catalyzed Multicomponent Reaction of Alkynes, Sulfonyl Azides and Diimines under Solvent-Free Conditions,SYNTHESIS-STUTTGART,2012年
  • 123. Regiospecific β-lactam ring-opening/recyclization reactions of N-aryl-3-spirocyclic-β-lactams catalyzed by a Lewis–Brønsted acids combined superacid catalyst system: a new entry to 3-spirocyclicquinolin-4(1H )-ones,CHEM COMMUN,2012年
  • 124. Copper-Mediated Chelation-Assisted Ortho Nitration of (Hetero)arenes,ORG LETT,2011年
  • 125. Fe(III)-Catalyzed Intermolecular C(sp²)-C(sp³) Dehydration Coupling Reaction of Ketene Dithioacetals and Propargyl Alcohols: Synthesis of Novel gem-Dialkylthiopenten-4-ynes and Further Conversion into Methyl Pent-4-ynoates,SYNLETT,2011年
  • 126. Copper-Catalyzed Dehydrogenative Cross-Coupling Reactions of N-para-Tolylamides through Successive C–H Activation: Synthesis of 4H-3,1-Benzoxazines,ANGEW CHEM INT EDIT,2011年
  • 127. Cu2O acting as a robust catalyst in CuAAC reactions: water is the required medium,GREEN CHEM,2011年
  • 128. Iron-Catalyzed Aminolysis of β-Carbonyl 1,3-Dithianes: Synthesis of Stereodefined β-Enaminones and 3,4-Disubstituted Pyrazoles,ORG LETT,2011年
  • 129. Iron-catalyzed synthesis of polysubstituted pyrroles via [4C+1N] cyclization of 4-acetylenic ketones with primary amines,CHEM COMMUN,2011年
  • 130. Catalytic intramolecular aromatic C–H alkenylation of arenas with non-activated ketones: synthesis of 4-alkylene quinolin-2-ones,CHEM COMMUN,2010年
  • 131. Affinity-Based Labeling of Cytohesins with a Bifunctional SecinH3 Photoaffinity Probe,ANGEW CHEM INT EDIT,2008年
  • 132. Intramolecular aza-anti-Michael addition of an amide anion to enones: a regiospecific approach to tetramic acid derivatives,ADV SYNTH CATAL,2007年
  • 133. Deoxo-Fluor [Bis(2-methoxyethyl) aminosulfur Trifluoride]: An Advanced Nucleophilic Fluorinating Reagent in Organic Synthesis,SYNLETT,2006年
  • 134. Efficient synthesis of highly functionalized dihydropyrido[2,3-d]pyrimidines by a double annulation strategy from alpha-alkenoyl-alpha-carbamoyl ketene-(S,S)-acetals,J ORG CHEM,2006年
  • 135. Thia-Michael Addition Reaction Using 2-[Bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides as Odorless and Efficient Thiol Equivalents,SYNLETT,2006年
  • 136. [5C + 1S] Annulation: A Facile and Efficient Synthetic Route toward Functionalized 2, 3-Dihydrothiopyran-4-ones,J ORG CHEM,2005年
  • 137. [5C + 1N] Annulation:a novel synthetic strategy for functionalized 2,3-dihydro-4-pyridones,CHEM COMMUN,2005年
  • 138. [5+1] Annulation:A Synthetic Strategy for Highly Substituted Phenols and Cyclohexenones,J AM CHEM SOC,2005年
  • 139. A Facile and Efficient Synthesis of 3,5-Disubstituted Tetronic Acids in Aqueous Media Involving Acid-Catalyzed Intramolecular Oxa-Pyridylethylation,SYNLETT,2005年
  • 专利:
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  • 一种三取代咪唑类化合物的合成方法 2019-01-08
  • 一种合成烯基叠氮孕酮的方法 2016-03-30
  • 一类有机小分子荧光染料的制备方法及其应用 2016-02-10
  • α-羟基烯基叠氮类化合物的合成方法 2015-06-17
  • 铜催化的咪唑并[1,2-a]吡啶-3-甲醛类化合物的合成方法 2015-06-03
  • 一种银催化的多取代吡咯类化合物的合成方法 2015-06-03
  • 一种环戊二烯的制备方法 2014-01-08
  • 铁催化的吡咯及吡咯并环类化合物的制备方法 2011-08-31
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